Two-electron redox chemistry of p-nitro- and p-cyanobenzene diazohydroxides. / McEvoy, James; Pham, Nhan; Le, Hong; Fernandez, Micah; Farmer, Ryan; Mahapatro, Surendra.

In: Rsc advances, Vol. 8, No. 73, 13.12.2018, p. 41762-41766.

Research output: Contribution to journalArticle

E-pub ahead of print

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Two-electron redox chemistry of p-nitro- and p-cyanobenzene diazohydroxides. / McEvoy, James; Pham, Nhan; Le, Hong; Fernandez, Micah; Farmer, Ryan; Mahapatro, Surendra.

In: Rsc advances, Vol. 8, No. 73, 13.12.2018, p. 41762-41766.

Research output: Contribution to journalArticle

Harvard

McEvoy, J, Pham, N, Le, H, Fernandez, M, Farmer, R & Mahapatro, S 2018, 'Two-electron redox chemistry of p-nitro- and p-cyanobenzene diazohydroxides', Rsc advances, vol. 8, no. 73, pp. 41762-41766. https://doi.org/10.1039/C8RA05948A

APA

McEvoy, J., Pham, N., Le, H., Fernandez, M., Farmer, R., & Mahapatro, S. (2018). Two-electron redox chemistry of p-nitro- and p-cyanobenzene diazohydroxides. Rsc advances, 8(73), 41762-41766. https://doi.org/10.1039/C8RA05948A

Vancouver

McEvoy J, Pham N, Le H, Fernandez M, Farmer R, Mahapatro S. Two-electron redox chemistry of p-nitro- and p-cyanobenzene diazohydroxides. Rsc advances. 2018 Dec 13;8(73):41762-41766. https://doi.org/10.1039/C8RA05948A

Author

McEvoy, James ; Pham, Nhan ; Le, Hong ; Fernandez, Micah ; Farmer, Ryan ; Mahapatro, Surendra. / Two-electron redox chemistry of p-nitro- and p-cyanobenzene diazohydroxides. In: Rsc advances. 2018 ; Vol. 8, No. 73. pp. 41762-41766.

BibTeX

@article{661a7bc3789a45d3b3a39b7c3d6d81c5,
title = "Two-electron redox chemistry of p-nitro- and p-cyanobenzene diazohydroxides",
abstract = "The electrochemistry of aryl diazonium salts is usually dominated by one-electron reduction, loss of dinitrogen, and the grafting of aryl radicals onto the electrode. In contrast, p-nitro- and p-cyanobenzene diazonium salts dissolved in mixed aqueous-acetonitrile solvents showed diffusion-limited, quasireversible, two-electron cyclic voltammetry. Voltammetric pH-dependence and spectrophotometric kinetic studies suggest that the basicity and low polarity of the aqueous solvent mixture has revealed the biologically-significant interconversion of diazohydroxide and diazene.",
author = "James McEvoy and Nhan Pham and Hong Le and Micah Fernandez and Ryan Farmer and Surendra Mahapatro",
year = "2018",
month = dec
day = "13",
doi = "10.1039/C8RA05948A",
language = "English",
volume = "8",
pages = "41762--41766",
journal = "Rsc advances",
issn = "2046-2069",
publisher = "Royal Society of Chemistry",
number = "73",

}

RIS

TY - JOUR

T1 - Two-electron redox chemistry of p-nitro- and p-cyanobenzene diazohydroxides

AU - McEvoy, James

AU - Pham, Nhan

AU - Le, Hong

AU - Fernandez, Micah

AU - Farmer, Ryan

AU - Mahapatro, Surendra

PY - 2018/12/13

Y1 - 2018/12/13

N2 - The electrochemistry of aryl diazonium salts is usually dominated by one-electron reduction, loss of dinitrogen, and the grafting of aryl radicals onto the electrode. In contrast, p-nitro- and p-cyanobenzene diazonium salts dissolved in mixed aqueous-acetonitrile solvents showed diffusion-limited, quasireversible, two-electron cyclic voltammetry. Voltammetric pH-dependence and spectrophotometric kinetic studies suggest that the basicity and low polarity of the aqueous solvent mixture has revealed the biologically-significant interconversion of diazohydroxide and diazene.

AB - The electrochemistry of aryl diazonium salts is usually dominated by one-electron reduction, loss of dinitrogen, and the grafting of aryl radicals onto the electrode. In contrast, p-nitro- and p-cyanobenzene diazonium salts dissolved in mixed aqueous-acetonitrile solvents showed diffusion-limited, quasireversible, two-electron cyclic voltammetry. Voltammetric pH-dependence and spectrophotometric kinetic studies suggest that the basicity and low polarity of the aqueous solvent mixture has revealed the biologically-significant interconversion of diazohydroxide and diazene.

UR - https://pubs.rsc.org/en/content/articlehtml/2018/RA/C8RA05948A

U2 - 10.1039/C8RA05948A

DO - 10.1039/C8RA05948A

M3 - Article

VL - 8

SP - 41762

EP - 41766

JO - Rsc advances

JF - Rsc advances

SN - 2046-2069

IS - 73

ER -